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Prier
Prier earns the demon overlord title when you run through the Dark World in La Pucelle Tactics and kill 10 Demon Overlords of level 500 and above. At the end of the 10 stages you get a cut-scene where many demons surround Prier, Culotte, and Alouette. The demons give Prier the title of Demon Overlord for defeating so many other overlords, at which point Culotte and Alouette walk away saying comments like, "You've lost your way Prier... You'll never become the Maiden of Light now." Prier meanwhile is just stunned and confused, then the credits roll showing her in Demon form. In Disgaea 1 when you unlock her as a secret character she is a Demon Overlord, so it's her after the secret ending from La Pucelle.
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